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An organic compound 'A' has the molecula...

An organic compound 'A' has the molecular formula `C_(3)H_(6)O`, it undergoes iodoform test. Whet satruated with HCl it gives 'B' of molecular foumula `C_(9)H_(14)O`. A and B, respectively are

A

Propanal and mesitylene

B

Propanone and mesityl oxide

C

Propanone and 2, 6-dimethyl-2, 5-heptadien-4-one.

D

Propanone and mesitylene oxide.

Text Solution

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The correct Answer is:
To solve the problem step by step, let’s analyze the information provided: ### Step 1: Identify Compound A The molecular formula of compound A is \( C_3H_6O \). Since it undergoes the iodoform test, it must contain a methyl ketone group (a carbonyl group adjacent to a methyl group). The only structure that fits this requirement with three carbon atoms is propanone (acetone). **Compound A:** Propanone (acetone) - \( CH_3COCH_3 \) ### Step 2: Determine the Reaction with HCl When propanone (A) is saturated with HCl, it undergoes an addition reaction. Given that the molecular formula of the resulting compound B is \( C_9H_{14}O \), we can infer that propanone likely forms a trimer (a compound made up of three molecules of propanone). ### Step 3: Identify Compound B The trimer of propanone can be represented as a cyclic compound. The molecular formula \( C_9H_{14}O \) suggests that the trimer is a compound with a ketone functional group. The structure of the cyclic trimer of propanone is known as 2,6-dimethyl-2,5-heptane-diene-4-one. **Compound B:** 2,6-dimethyl-2,5-heptane-diene-4-one ### Conclusion Thus, the compounds A and B are: - **A:** Propanone (acetone) - **B:** 2,6-dimethyl-2,5-heptane-diene-4-one

To solve the problem step by step, let’s analyze the information provided: ### Step 1: Identify Compound A The molecular formula of compound A is \( C_3H_6O \). Since it undergoes the iodoform test, it must contain a methyl ketone group (a carbonyl group adjacent to a methyl group). The only structure that fits this requirement with three carbon atoms is propanone (acetone). **Compound A:** Propanone (acetone) - \( CH_3COCH_3 \) ### Step 2: Determine the Reaction with HCl ...
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