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The soldiers of Napoleon army while at A...

The soldiers of Napoleon army while at Alps during freezing winter suffered a serious problem with regard to the tin buttons of their uniform. White metallic tin buttons get converted to grey poweder. This transformation is relate to

A

an interaction with nitrogen of the air at very low temperatures

B

a change in the crystalline struture of tin

C

a change in the partial pressure of oxygen in the air

D

an interaction with water vapour contained in the humid air

Text Solution

Verified by Experts

The correct Answer is:
B

Transitin of white to grey tin occurs at any temperature below `15.2^(@)C`, it becomes rapid at `-50^(@)C` . The conversion of white tin to grey tin (as in cold countries) is accompanied by an increases in volume and the latter, being very brittle, easily crumbles down to powder (a charge in crystallines structure of tin).
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Soldiers of Napolean army while at alps during freezing winter suffered a serious problem as regards to the tin buttons of their uniforms. White metallic tin buttons got converted to grey powder. This transformation is related to