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Which one of the following does not unde...

Which one of the following does not undergo hydrolysis?

A

`AsCl_(3)`

B

`SbCl_(3)`

C

`PCl_(3)`

D

`NF_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound does not undergo hydrolysis among the given options, we will analyze each compound based on their chemical properties and the presence of vacant d orbitals. ### Step-by-Step Solution: 1. **Understanding Hydrolysis**: Hydrolysis is a chemical reaction involving water that leads to the breakdown of a compound. For a compound to undergo hydrolysis, it typically requires the central atom to have vacant d orbitals to accommodate the lone pairs of electrons from water molecules. 2. **Analyzing the Compounds**: - **Option 1: AlCl3 (Aluminum Chloride)**: - Aluminum has vacant d orbitals and can accept lone pairs from water, thus it undergoes hydrolysis to form Al(OH)3. - **Option 2: SbCl3 (Antimony Trichloride)**: - Antimony also has vacant d orbitals and can undergo hydrolysis, forming Sb(OH)3. - **Option 3: PCl3 (Phosphorus Trichloride)**: - Phosphorus can undergo hydrolysis as it has vacant d orbitals, leading to the formation of H3PO3. - **Option 4: NF3 (Nitrogen Trifluoride)**: - Nitrogen does not have vacant d orbitals. Therefore, it cannot accept lone pairs from water and does not undergo hydrolysis. 3. **Conclusion**: Based on the analysis, the compound that does not undergo hydrolysis is **NF3 (Nitrogen Trifluoride)**. ### Final Answer: **NF3 does not undergo hydrolysis.**

To determine which compound does not undergo hydrolysis among the given options, we will analyze each compound based on their chemical properties and the presence of vacant d orbitals. ### Step-by-Step Solution: 1. **Understanding Hydrolysis**: Hydrolysis is a chemical reaction involving water that leads to the breakdown of a compound. For a compound to undergo hydrolysis, it typically requires the central atom to have vacant d orbitals to accommodate the lone pairs of electrons from water molecules. 2. **Analyzing the Compounds**: - **Option 1: AlCl3 (Aluminum Chloride)**: ...
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