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Nitrogen forms N(2) but phosphorous when...

Nitrogen forms `N_(2)` but phosphorous when forms `P_(2)` gets readily converted into `P_(4)` because

A

triple bond is present between phosphorus atoms

B

`p pi -d pi ` bonding is weak

C

`p pi- p pi` bonding is strong

D

multiple bond is formed easily.

Text Solution

Verified by Experts

The correct Answer is:
B

`P_(2)` is unstable because the `p pi -d pi ` bonding in it is weak. It is due to larger atomic size of P and N. thus `P_(2)` is converted into `P_(4)` in which there is no `p pi -dpi` bonding.
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DINESH PUBLICATION-THE NITROGEN FAMILY-Revision question
  1. Which has the lowest boiling point?

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  2. The basicity of phosphorus acid (H3 PO3) is .

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  3. Nitrogen forms N(2) but phosphorous when forms P(2) gets readily conve...

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  4. P4 O(10) is not used to dry NH3 gas because

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  5. In which of the following bond angle is maximum

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  6. Aqueous sodium hydroxide reacts with white phosphorus to form phosphin...

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  7. The stability of the hydrides follows the order

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  8. Which one of the following arrangements of molecules is correct on the...

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  9. Ionic radii (in Ã…) of As^(3+), Sb^((3+) and Bi^(3+) follow the order

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  10. The trade name of sodium hexametaphosphate is.

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  11. Which one of the following is an oxyacid ?

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  12. The explanation for the presence of three unpaired electrons in the ni...

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  13. When on excess of chlorine is treated with ammonia ,the products forme...

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  14. The three important oxidation states of phosphorus are

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  15. Of the following compounds, the most acidic is

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  16. Which one of the following elements is most metallic?

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  17. Number of sigma bonds in P4 O(10) is :

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  18. In NO3^- ion, the number of bond pair and lone pair of electrons no N-...

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  19. In the following reaction PCl5 overset(H2 O) to HCl + A

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  20. PH3, the hydride of phosphorus is

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