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Which of the following is not soluble in...

Which of the following is not soluble in excess of water ?

A

`AsCl_(3)`

B

`SbCl_(3)`

C

`BiCl_(3)`

D

both (B) and (C)

Text Solution

Verified by Experts

The correct Answer is:
D
Both `SbCl_(3)` and `BiCl_(3)` are not soluble in excess of water. It is due to the formation of insoluble SbOCl and BiOCl on partial hydrolysis.
`SbCl_(3)+H_(2)O to SbOCl darr+2HCl`
`BiCl_(3)+H_(2)O to BiOCl darr +2HCl`
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