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When potassium ferrocyanide crystals are...

When potassium ferrocyanide crystals are heated with concentrated sulphuric acid, the gas evolved is

A

`SO_2`

B

`NH_3`

C

`CO_2`

D

CO

Text Solution

Verified by Experts

The correct Answer is:
D

`K_4Fe(CN)_6` with conc. `H_2SO_4` gives CO.
`({:(K_4Fe(CN)_6+3H_2SO_4to,2K_2SO_4+FeSO_4+6HCN),(HCN+2H_2Oto,HCOOH+NH_3"]"xx6),(HCOOHoverset("conc."H_2SO_4)to,H_2O+CO"]"xx6),(2NH_3+H_2SO_4to,(NH_4)_2SO_4"]"xx3):})/ul(K_4Fe(CN)_6+6H_2SO_4+6H_2Oto2K_2SO_4+FeSO_4+6CO+3(NH_4)_2SO_4)`
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