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The oxidation states of sulphur in the a...

The oxidation states of sulphur in the anions `SO_(3)^(2-), S_(2)O_(4)^(2-)`, and `S_(2)O_(6)^(2-)` follow the order

A

`S_2O_6^2 lt S_2O_4^2 lt SO_3^2`

B

`S_2O_4^2 lt SO_3^2 lt S_2O_6^2`

C

`SO_3^2 lt S_2O_3^2 lt S_3O_6^2`

D

`S_2O_4^2 lt S_2O_6^2 lt SO_3^2`

Text Solution

Verified by Experts

The correct Answer is:
B

O.S. of S in `SO_3^(2-)= +4`
O.S. of S in `S_2O_4^(2-)= +3`
O.S. of S in `S_2O_6^(2-)= +5`
(None of these contains peroxide linkage. )
The correct order of increasing O.S. is ,
`S_2O_4^(2-) lt SO_3^(2-) lt S_2O_6^(2-)`
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