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In which of the following pairs, the two...

In which of the following pairs, the two species are isostructural :

A

`BrO_3^(-) and XeO_3`

B

`SF_4 and XeF_4`

C

`SO_3^(2-) and NO_3^(2-)`

D

`BF_3 and NF_3`

Text Solution

Verified by Experts

The correct Answer is:
A

`BrO^-` and `XeO_3` are both pyramidal. All others have different geometries. For example, `SF_4` is trigonal bipyramidal and `XeF_4` is square planar, `SO_3^(2-)` is pyramidal while `NO_3^-` is trigonal planar: `BF_3` is trigonal planar and `NF_3` is pyramidal
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