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Which of the following is most likely st...

Which of the following is most likely structure of `CrO_(3).6H_(2)O` if `1//3` of total chlorine of the compound is precipitated by adding `AgNO_(3)` to its aqueous solution ?

A

`CrCl_(3).6H_(2)O`

B

`[Cr(H_(2)O)_(3)Cl_(3)](H_(2)O)_(3)`

C

`[CrCl_(2)(H_(2)O)_(4)]Cl.2H_(2)O`

D

`[CrCl.(H_(2)O)_(5)]Cl_(2).H_(2)O`

Text Solution

Verified by Experts

The correct Answer is:
C
Out of `3` `Cl` atoms, only one `Cl` atom is ionisable. The other two `Cl` atoms are part of coordination sphere . Hence its structure is `[CrCl_(2)(H_(2)O)_(4)]Cl.2H_(2)O`
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