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Which of the following complex will give...

Which of the following complex will give white ppt. with `BaCl_(2)` solution ?

A

`[Cr(NH_(3))_(5)SO_(4)]Cl`

B

`[Co(NH_(3))_(4)Cl_(2)]NO_(2)`

C

`[Cr(NH_(3))_(5)Cl]SO_(4)`

D

Both A and C

Text Solution

Verified by Experts

The correct Answer is:
C
`[Cr(NH_(3))_(5)Cl]SO_(4)hArr [Cr(NH_(3))_(5)Cl]^(2+) + SO_(4)^(2-)`
`SO_(4)^(2-)` ions form precipitate with `BaCl_(2)` solution.
`SO_(4)^(2-) + BaCl_(2)(aq)rarr underset(ppt) (BaSO_(4))darr + 2Cl^(-)(aq)`
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