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The correct IUPAC name of K(2)[Zn(OH)(4)...

The correct IUPAC name of `K_(2)[Zn(OH)_(4)]` is

A

potassium tetrahydroxyzinc(II)

B

potassium tetrahydroxozincate(II)

C

potassium tetrahydroxizincate(IV)

D

potassium hydroxozinc(II)

Text Solution

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The correct Answer is:
To determine the correct IUPAC name of the coordination compound \( K_2[Zn(OH)_4] \), we will follow the systematic naming rules for coordination compounds. Here’s a step-by-step breakdown of the solution: ### Step 1: Identify the Cation and Anion The compound \( K_2[Zn(OH)_4] \) consists of: - Cation: \( K^+ \) (potassium) - Anion: \( [Zn(OH)_4]^{2-} \) ### Step 2: Name the Cation The cation is potassium, and since there are two potassium ions, we simply write "potassium" in the name. ### Step 3: Identify the Ligands The anionic part \( [Zn(OH)_4]^{2-} \) contains hydroxide ions (OH\(^-\)). Hydroxide is a negatively charged ligand, and since there are four hydroxide ligands, we use the prefix "tetra-" to indicate the number of ligands. ### Step 4: Name the Ligands The ligand derived from hydroxide is called "hydroxo." Since there are four hydroxide ligands, we write "tetrahydroxo." ### Step 5: Name the Central Metal The central metal ion is zinc. Since it is part of an anionic complex, we modify the name of zinc to "zincate." ### Step 6: Determine the Oxidation State of the Metal To find the oxidation state of zinc in the complex, we can set up the following equation based on the charges: - Let the oxidation state of zinc be \( x \). - The total charge contributed by the four hydroxide ligands is \( -4 \) (since each hydroxide has a charge of -1). - The overall charge of the anionic complex is \( -2 \). Thus, we have: \[ x - 4 = -2 \] Solving for \( x \): \[ x = +2 \] ### Step 7: Combine All Parts Now we can combine all parts to form the complete name: - Cation: potassium - Ligands: tetrahydroxo - Central metal: zincate - Oxidation state: (II) Putting it all together, the IUPAC name is: **Potassium tetrahydroxozincate(II)** ### Final Answer The correct IUPAC name of \( K_2[Zn(OH)_4] \) is **Potassium tetrahydroxozincate(II)**. ---

To determine the correct IUPAC name of the coordination compound \( K_2[Zn(OH)_4] \), we will follow the systematic naming rules for coordination compounds. Here’s a step-by-step breakdown of the solution: ### Step 1: Identify the Cation and Anion The compound \( K_2[Zn(OH)_4] \) consists of: - Cation: \( K^+ \) (potassium) - Anion: \( [Zn(OH)_4]^{2-} \) ### Step 2: Name the Cation ...
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