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From the following given co-ordination c...

From the following given co-ordination compounds find the odd one out
`[Ag(NH_(3))_(2)]^(+)`, `[AgCl_(2)]^(-)`, `[Ag(CN_(2)]^(-)`, `[Ag(CN)_(4)]^(2-)`

A

`[Ag(NH_(3))_(2)]^(+)`

B

`[AgCl_(2)]^(-)`

C

`[Ag(CN)_(2)]^(-)`

D

`[Ag(CN)_(4)]^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
D
Silver has shown a coordination number of four
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Coordination compounds plays many important roles in animals and plants. The are essential in the storage and transport of oxygen as electrons transfer agents as catalysts and in photosynthesis Wide range of application in daily life takes place through formation of complexes Photographic fixing qualitative and quantitative analysis purification of water metallurgical extraction are some specific worth mentioning Extraction of Ag from sulphide ore and removal of unreacted silver from photographic plate involve complexes: (a) [Ag(S_(2)O_(3))_(2)]^(3-) ion both (b) [Ag(CN)_(2)]^(Θ) in both (c) [Ag(S_(2)O_(3))]^(3-) , [Ag(CN)_(2)]^(Θ) (d) [Ag(CN)_(2)]^(Θ) ,[Ag_(2)(S_(2)O_(3))_(2)]^(3-) .