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Chemical formula for in iron(III) hexacy...

Chemical formula for in iron(III) hexacyanoferrate(II) is

A

`Fe^3^+[Fe(CN)_(6)]^4^-`

B

`Fe_(3)[Fe(CN)_(6)]`

C

`Fe_(3)[Fe(CN)_(6)]_(4)`

D

`Fe_(4)[Fe(CN)_(6)]^(3)`

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The correct Answer is:
To determine the chemical formula for iron(III) hexacyanoferrate(II), we can follow these steps: ### Step 1: Identify the oxidation states The name "iron(III)" indicates that iron (Fe) has an oxidation state of +3. The "ferrate(II)" indicates that the other iron in the complex has an oxidation state of +2. **Hint:** Look for the oxidation states indicated in the name of the compound. ### Step 2: Identify the ligands and their counts The term "hexacyano" indicates that there are six cyanide (CN⁻) ligands. The prefix "hexa-" means six. **Hint:** Pay attention to the prefixes in the name to determine the number of ligands. ### Step 3: Write the formula for the anionic part The anionic part is derived from the ligands and the oxidation state of the metal. Since there are six cyanide ligands, the charge contributed by the cyanide ligands is -6 (since each CN⁻ has a charge of -1). Therefore, the anionic part can be represented as [Fe(CN)₆] with a total charge of -4 (since the overall charge of the complex must balance with the +3 from iron(III)). **Hint:** Combine the ligands with their charges to form the anionic part of the complex. ### Step 4: Combine the cationic and anionic parts The cationic part is Fe³⁺ (from iron(III)), and the anionic part is [Fe(CN)₆]⁴⁻ (from hexacyanoferrate(II)). To write the complete formula, we combine these two parts. **Hint:** Ensure that the total charge of the complex is neutral when combining cationic and anionic parts. ### Step 5: Write the final formula The final formula for iron(III) hexacyanoferrate(II) can be represented as: \[ \text{Fe}^{3+}[\text{Fe(CN)}_6]^{4-} \] This can be simplified to: \[ \text{Fe}_3[\text{Fe(CN)}_6]_2 \] **Hint:** Check if the charges balance out to zero when writing the final formula. ### Final Answer The chemical formula for iron(III) hexacyanoferrate(II) is: \[ \text{Fe}_3[\text{Fe(CN)}_6]_2 \]

To determine the chemical formula for iron(III) hexacyanoferrate(II), we can follow these steps: ### Step 1: Identify the oxidation states The name "iron(III)" indicates that iron (Fe) has an oxidation state of +3. The "ferrate(II)" indicates that the other iron in the complex has an oxidation state of +2. **Hint:** Look for the oxidation states indicated in the name of the compound. ### Step 2: Identify the ligands and their counts ...
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Chemical Formulas

The formula for iron (III) hexacyanoferrate(II), commonly known as Prussian blue, is 1. Fe_3[Fe(CN)_6]_2 2. Fe_2[Fe(CN)_6]_3 3. Fe_4[Fe(CN)_6]_3 4. Fe_3[Fe(CN)_6]_4

Write the molecular formula of iron (Ill) hexacyanidoferrate (II).

DINESH PUBLICATION-CO-ORDINATION COMPOUNDS -REVISION QUESTIONS
  1. Which of the following complexes will have four isomers ?

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  2. The correct structure of Fe(CO)(5) is (Z= 26 for Fe)

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  3. Chemical formula for in iron(III) hexacyanoferrate(II) is

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  4. The shape of [Cu(NH(3))(4)]^(2+) is

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  5. The EAN of iron in [Fe(CN)(6)]^(3-) is

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  6. CuSO(4) dissolves in NH(3) due to formation of

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  7. Which one of the following is an example of octahedral complex ?

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  8. K(4)[Fe(CN)(6)] is a

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  9. Which of the following is paramagnetic?

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  10. Magnesium is an important component of which biomolecule occuring exte...

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  11. The valency of Cr in the complex [Cr(H(2)O)(4)Cl(2)]^(+)

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  12. Which of the following is expected to be a paramagnetic complex?

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  13. IUPAC name of Na(3)[Co(NO(2))(6)] is

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  14. According to the postulates of Werner for cooedination compounds

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  15. Correct formula of the complex formed in the brown ring test for nitra...

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  16. AgCl is soluble in NH(4)OH solution. The solubility is due to the form...

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  17. The number of isomers exhibited by [Cr(NH(3))(3)Cl(3)] is

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  18. For the square planar complex [M(a) (b) (c ) (d)] (where M = central m...

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  19. Which of the following will exhibit optocal isomerism ?

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  20. In Zeigler-Natta polymerisation of ethylene, the active species is

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