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Ammonia forms the complex [Cu(NH3)4]^(2+...

Ammonia forms the complex `[Cu(NH_3)_4]^(2+)` with copper ions in alkaline solution but not in acid solution. The reasons for it is:

A

In acidic solution hydration protects `Cu^(2+)` ion

B

In acidic solution proton coordinates with ammonia molecules to form `NH_(4)^(+)` ions and `NH_(3)` molecules are not available

C

In alkaline solutions insoluble `Cu(OH)_(2)` is precipitated which is soluble in excess of any alkali.

D

Copper hydroxide is amphorteric substance.

Text Solution

Verified by Experts

The correct Answer is:
D

In acidic solution proton coordinates with ammonia molecules to form `NH_(4)^(+)` ions and `NH_(3)` molecules are not aveilable for complex show formation .
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