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In nitroprusside ion, the iron and NO ex...

In nitroprusside ion, the iron and `NO` exist as `Fe(II)` and `NO^(+)` rather than `Fe^(III)` and `NO`. These forms can be differentiated by

A

estimating the concentration of iron

B

measuring the concentration of `CN^(-)`

C

measuring the solid state magnetic monent

D

thermally decomposing the compound.

Text Solution

Verified by Experts

The correct Answer is:
C

Oxidation state of iron `(+2 or +3)` can be checked by measuring solid state magnetic moment.
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DINESH PUBLICATION-CO-ORDINATION COMPOUNDS -SELECTED STRAIGHT OBJECTIVE TYPE MCQS
  1. Among the following ions, which one has the highest paramagnetism?

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  2. Which of the following is an organometallic compound ?

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  3. In nitroprusside ion, the iron and NO exist as Fe(II) and NO^(+) rathe...

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  4. The geometry of Ni(CO(4)) and Ni(PPh(3))(2)Cl(2) are

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  5. The pair having the same magnetic moment is [at. No. Cr = 24, Mn = ...

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  6. The correct order of hybridisation of the central atom in the followin...

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  7. A mixture x containing 0.02 mol of [Co(NH(3))(5) SO(4)]Br and 0.02 mol...

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  8. In the process of extraction of gold. Roasted gold ore +CN^(-)+H(2)O...

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  9. The pair of the compounds in which both the metals are in the highest ...

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  10. The species having tetrahedral shape is

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  11. Which kind of isomerism is shown by Co (NH(3))(4) Br(2) Cl ?

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  12. In which of the following pairs both the complexes do not show optical...

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  13. The diamagnetic species is

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  14. The correct order for the wavelength of absorption in the visible regi...

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  15. Which of the following compounds show optical isomerism?

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  16. Which one of the cyano complexes would exhibit the lowest value of par...

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  17. Which of the following is an inner orbital complex as well as diamagne...

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  18. Which one of the following is expected to exhibit optical isomerism (e...

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  19. IUPAC name [Co(NH(3))(5)(NO(2))]Cl(2) is

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  20. Nickel (Z=28) combines with a uninegative monodentate ligand X^(-) to ...

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