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Ag^(+)+hArr|Ag(NH(3))(2)|^(+), k(1) = 6....

`Ag^(+)+hArr|Ag(NH_(3))_(2)|^(+), k_(1) = 6.8 xx 10^(-3)`
`[Ag(NH_(3))]^(+) + NH_(3)hArr |Ag(NH_(3))_(2)|, k_(2) = 1.6xx10^(-3)`
Then the formation constant or `|Ag(NH_(3))_(2)|^(+)` is

A

`1.08 xx 10^(-7)`

B

`1.08 xx 10^(-5)`

C

`1.08 xx 10^(-9)`

D

none of these

Text Solution

Verified by Experts

The correct Answer is:
B

As the reaction takes place in two stages
`k = k_(1)xx k_(2) = (6.8 xx 10^(-3)) xx (1.6xx 10^(-3))`
= `10.8 xx 10^(-6) = 1.08xx 10^(-5)`
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If Ag^(+)+NH_(3)hArr[Ag(NH_(3))]^(+) , K_(1)=3.5xx10^(-3) and [Ag(NH_(3))]^(+)+NH_(3)hArr[Ag(NH_(3))_(2)]^(+) , K_(2)=1.74xx10^(-3) . The formation constant of [Ag(NH_(3))_(2)]^(+) is :

Ag^(+) + NH_(3) ltimplies [Ag(NH_(3))]^(+), k_(1)=6.8 xx 10^(-5) [Ag(NH_(3))]^(+) + NH_(3) ltimplies [Ag(NH_(3))_(2)]^(+) , k_(2) = 1.6xx10^(-3) The formation constant of [Ag(NH_(3))_(2)]^(+) is :

Ag^(+)+NHP(3)hArr[Ag(NH_(3))]^(+), K_(1)=3.5=10^(-3) [Ag(NH)_(3)]^(+)+NH_(3)hArr[Ag(NH_(3))_(2)]^(+),K_(2)=1.7xx10^(-3) then the formation constant of [Ag(NH_(3))_(2)]^(+) is

Zn^(+2) + 2NH_(3) hArr [Zn(NH_(3))_(2)]^(+2), K_(1) = 2xx10^(-3) [Zn(NH_(3))_(2)]^(+2) + 2NH_(3) hArr [Zn(NH_(3))_(4)]^(2+), K_(2) = 1.5xx10^(-3) Find out the instability constant?

{:(Ag^+ +NH_3 hArr[Ag(NH_3)]^+,,K_1=3.5xx10^-3),([Ag(NH_3)]^+ +NH_3 hArr[Ag(NH_3)_2]^+,,K_2=1.8xx10^-3):} then, the overall formation constant of [Ag(NH_3)_2]^+ is :

The hybridization of Ag in the linear complex [Ag(NH_(3))_(2)]^(+) is

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