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For the given complex [CoCl(2)(en)(N(3))...

For the given complex `[CoCl_(2)(en)(N_(3))_(2)]^(+)`, the number of geometrical iosmers, the number of optical isomers and total number of isomers of all type possible respectively are

A

2, 2 and 4

B

2 ,2 and 3

C

2, 0 and 2

D

0, 2 and 1

Text Solution

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The correct Answer is:
B

The octahedral complex of the type `[M(A A)(x_(2)y_(2))]` i.e. `|CoCl_(2)(en)(NH_(3))_(2)|^(+)` will show two cis and trans isomers . Out of these , cis isomer will be optical active and shows two d & l forms . So the total number of possible isomers will be three .
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DINESH PUBLICATION-CO-ORDINATION COMPOUNDS -SELECTED STRAIGHT OBJECTIVE TYPE MCQS
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