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Which of the following complex ions is e...

Which of the following complex ions is expected to absorb visible light?

A

`|Ti(en)_(2)(NH_(3))_(2)|^(4+)`

B

`|Cr(NH_(3))_(6)|^(3+)`

C

`|Zn(NH_(3))_(6)|^(2+)`

D

`|Sc(H_(2)O)_(3)(NH_(3))_(3)|^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
B

`d^(0)(Ti^(4+), Sc^(3+)` )and `d^(10)(Zn^(2+))` species will not absorb visible light and are colourless. `d^(3)(Cr^(3+))` can unbergo d-d-transition on absorption of visibla light of a particular wave length and will be coloured.
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DINESH PUBLICATION-CO-ORDINATION COMPOUNDS -SELECTED STRAIGHT OBJECTIVE TYPE MCQS
  1. The spin only magnetic moment value of Cr(CO)(6) is

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  2. The magnitude of crystal field stabilization energy (CFSE or Deltat) i...

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  3. Which of the following complex ions is expected to absorb visible ligh...

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  4. When EDTA solution is added to Mg^(2+) ion solution, then which of the...

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  5. The correct structure of ethylenediamineteraacetic acid (EDTA) is .

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  6. Which one of the following complex is not expected to exhibit isomeris...

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  7. The existence of two different coloured comlexes with the composition ...

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  8. Which of the following is wrongly matched?

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  9. Which of the following complex has minimum magnitude of Delta^(0) ?

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  10. Crystal field stabilization energy for high spin d^4 octahedral comple...

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  11. Which of the following is diamagnetic in nature ?

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  12. In Fe(CO)(5), the Fe larr CO sigma bond results by the overlap between...

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  13. The ligand N(CH(2)CH(2)NH(2))(3) is

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  14. Which one of the following has largest number of isomers?

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  15. Square planar complexes of the type MABXL (where A, B, X and L are uni...

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  16. Which of the following complex ions has geometrical isomers?

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  17. Which 0.01 mole of a cobalt complex is treated with excess silver nitr...

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  18. The correct statement with respect to the complexes Ni(CO)(4) and |Ni(...

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  19. The complex which has the highest magnetic moment among the following ...

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  20. Among |Ni(CO)(4)|, |Ni(CN)(4)|^(2-), |NiCl(4)|^(2-) species, the hybri...

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