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Which of the following is diamagnetic in...

Which of the following is diamagnetic in nature ?

A

`Co^(3+)` , octahedral complex with weak field ligands

B

`Co^(3+)`, octahedral complex with strong field ligands

C

`Co^(2+)` in tetrahedral complex

D

`Co^(2+)` in a square planar complex.

Text Solution

Verified by Experts

The correct Answer is:
B

`_(27)Co = 3d^(7)4s^(2), Co^(3+)` = `3d^(6)4s^(0)`

In a strong field ligand , electrons pair up.
`:.`It is diamagnetic in nature.
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DINESH PUBLICATION-CO-ORDINATION COMPOUNDS -SELECTED STRAIGHT OBJECTIVE TYPE MCQS
  1. Which of the following complex has minimum magnitude of Delta^(0) ?

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  2. Crystal field stabilization energy for high spin d^4 octahedral comple...

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  3. Which of the following is diamagnetic in nature ?

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  4. In Fe(CO)(5), the Fe larr CO sigma bond results by the overlap between...

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  5. The ligand N(CH(2)CH(2)NH(2))(3) is

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  6. Which one of the following has largest number of isomers?

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  7. Square planar complexes of the type MABXL (where A, B, X and L are uni...

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  8. Which of the following complex ions has geometrical isomers?

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  9. Which 0.01 mole of a cobalt complex is treated with excess silver nitr...

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  10. The correct statement with respect to the complexes Ni(CO)(4) and |Ni(...

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  11. The complex which has the highest magnetic moment among the following ...

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  12. Among |Ni(CO)(4)|, |Ni(CN)(4)|^(2-), |NiCl(4)|^(2-) species, the hybri...

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  13. Geometrical shapes of the complex formed by the reaction of Ni^(2+) wi...

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  14. Among the following complexes : K(3)[Fe(CN)(6)],[Co(NH(3))(6)]Cl(3) , ...

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  15. Which of the following facls about the complex |Cr(NH(3))(6)|Cl(3) is ...

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  16. Low spin complex of d^6-cation in an octahedral field will have the fo...

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  17. [NiCl(2){P(C(2)H(5))(2)(C(6)H(5))}(2)] exhibits temperature dependent ...

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  18. Which one of the following is an outer orbital complex and exhibits pa...

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  19. As per IUPAC nomenclature, the name of the complex [Co(H(2)O)(4) (NH(3...

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  20. Which of the following complex species is not expected to exhibit opti...

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