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The correct statement with respect to th...

The correct statement with respect to the complexes `Ni(CO)_(4) and |Ni(CN)_(4)|^(2-)` is

A

nickel is in the same oxidation state in both

B

both have tetrahedral geometry

C

both have square planar geometry

D

have tetrahedral and square planar geometry respectively.

Text Solution

Verified by Experts

`Ni(CO)_(4)rarrsp^(3)"hybridisation"rarr"tatrahedral"`
`|Ni(CN)_(4)|^(2-)rarrdsp^(2)"hybridisation"rarr "square planar"`
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DINESH PUBLICATION-CO-ORDINATION COMPOUNDS -SELECTED STRAIGHT OBJECTIVE TYPE MCQS
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  2. The ligand N(CH(2)CH(2)NH(2))(3) is

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  3. Which one of the following has largest number of isomers?

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  4. Square planar complexes of the type MABXL (where A, B, X and L are uni...

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  5. Which of the following complex ions has geometrical isomers?

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  6. Which 0.01 mole of a cobalt complex is treated with excess silver nitr...

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  7. The correct statement with respect to the complexes Ni(CO)(4) and |Ni(...

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  8. The complex which has the highest magnetic moment among the following ...

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  9. Among |Ni(CO)(4)|, |Ni(CN)(4)|^(2-), |NiCl(4)|^(2-) species, the hybri...

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  10. Geometrical shapes of the complex formed by the reaction of Ni^(2+) wi...

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  11. Among the following complexes : K(3)[Fe(CN)(6)],[Co(NH(3))(6)]Cl(3) , ...

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  12. Which of the following facls about the complex |Cr(NH(3))(6)|Cl(3) is ...

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  13. Low spin complex of d^6-cation in an octahedral field will have the fo...

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  14. [NiCl(2){P(C(2)H(5))(2)(C(6)H(5))}(2)] exhibits temperature dependent ...

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  15. Which one of the following is an outer orbital complex and exhibits pa...

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  16. As per IUPAC nomenclature, the name of the complex [Co(H(2)O)(4) (NH(3...

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  17. Which of the following complex species is not expected to exhibit opti...

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  18. An excess of AgNO(3) is added to 100mL of a 0.01M solution of dichloro...

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  19. Consider the follwing complexes ion P,Q and R P =[FeF(6)]^(3-), Q=[V...

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