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A complex PtCl(4).5NH(3) shows a molar c...

A complex `PtCl_(4).5NH_(3)` shows a molar conductance of 402 `ohm^(-1)cm^(2) mol^(-1)` in water and precipitate three mole of AgCl with `AgNO_(3)` . The formula of the complex is

A

`[Pt(NH_(3))_(6)Cl_(4)`

B

`[Pt(NH_(3))_(5)Cl]Cl_(3)`

C

`[Pt(NH_(3))_(4)Cl_(2)]Cl_(2)`

D

`[Pt(NH_(3))_(3)Cl_(3)]Cl`.

Text Solution

Verified by Experts

Molar conductance of 402 `ohm^(-1) cm^(2) mol^(-1)` indicate four ions so the formula is `[Pt(NH_(3))_(5)Cl]Cl_(3)` i.e., three `Cl^(-)` ions can be precipitated.
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