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Which of the following statements is inc...

Which of the following statements is incorrect?

A

In equilibrium mixture of ice and water kept in perfectly insulated flask mass of ice and water do not change with time.

B

the intensity of red colur increases when oxalic acid is added to a solution containing iron (III) nitrate and potassium thiocyanate.

C

On addition of catalyst. The equilibrium constant value is not affected.

D

equilibrim constant for a reaction with negative `DeltaH` value dcreases as the temperature increases.

Text Solution

Verified by Experts

The statement is incorrect. The reaction taking place in solution is :
`Fe^(3+) (aq) + 3 SCN^(-) (aq) hArr Fe (SCN)_(3)`
Red colour
Oxalic acid `(H_(2)C_(2)O_(4))` reacts with `Fe^(3+) (aq)` present in solution to from complex `Fe (SCN)_(3)`. AS a result the concentration of `Fe^(3+)` ions in the solution decreases and the intensity of red colour decreases.
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