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The ionisation cosntabnt of an acid, K(a...

The ionisation cosntabnt of an acid, `K_(a)` is the meaure of strength of an acid. The `K_(a)` values of acetic acid, hypochlorous acid and formic acid are `1.74xx10^(-5)`, `3.0xx10^(-8)` and `1.8xx10^(-4)` respectively. Which of the following orders of ph of `0.1` mol `dm^(-3)` solutions of these acids is correct ?

A

acetic acid gt hypochlorous acid gt formic acid

B

hypochlorous acid gt acetic acid gt formic acid

C

formic gt hypochlorous acid gt acetic acid

D

formic acid gt acetic acid gt hypochlorous acid

Text Solution

Verified by Experts

The correct Answer is:
B

We know that
`[H^(+)]=sqrt(K_(a)xxc)`
and `ph ="log"(1)/([H^(+)]`
This means that greater the `K_(a)`, stronger is t he acid and lesser is the ph of the solution. Therefore, (b) is the correct order of decreasing ph values.
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