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If the equilibrium constant for N(2) ...

If the equilibrium constant for
`N_(2) (g) + O_(2)(g) hArr 2NO(g)` is K , the equilibrium
`" constant for " 1/2 N_(2) (g) +1/2 O_(2) (g) hArr NO (g)` will be

A

`1/2 K`

B

`K`

C

`K^(2)`

D

`K^(1//2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to understand how equilibrium constants change when the stoichiometry of the reaction is altered. ### Step-by-Step Solution: 1. **Identify the Given Reaction and its Equilibrium Constant**: The first reaction is: \[ N_2(g) + O_2(g) \rightleftharpoons 2NO(g) \] The equilibrium constant for this reaction is given as \( K \). 2. **Write the Expression for the Equilibrium Constant**: The equilibrium constant \( K \) for the above reaction can be expressed as: \[ K = \frac{[NO]^2}{[N_2][O_2]} \] 3. **Consider the Modified Reaction**: The modified reaction we need to analyze is: \[ \frac{1}{2}N_2(g) + \frac{1}{2}O_2(g) \rightleftharpoons NO(g) \] We denote the equilibrium constant for this reaction as \( K' \). 4. **Relate the Modified Reaction to the Original Reaction**: The modified reaction is essentially half of the original reaction. When the coefficients in a balanced equation are multiplied by a factor, the equilibrium constant is raised to the power of that factor. 5. **Determine the New Equilibrium Constant**: Since the coefficients in the modified reaction are all halved (i.e., multiplied by \( \frac{1}{2} \)), the new equilibrium constant \( K' \) can be expressed in terms of \( K \): \[ K' = K^{\frac{1}{2}} = \sqrt{K} \] ### Final Answer: Thus, the equilibrium constant for the reaction \( \frac{1}{2}N_2(g) + \frac{1}{2}O_2(g) \rightleftharpoons NO(g) \) is: \[ K' = \sqrt{K} \]

To solve the problem, we need to understand how equilibrium constants change when the stoichiometry of the reaction is altered. ### Step-by-Step Solution: 1. **Identify the Given Reaction and its Equilibrium Constant**: The first reaction is: \[ N_2(g) + O_2(g) \rightleftharpoons 2NO(g) ...
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