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The equivalent mass of MnSO(4) is half i...

The equivalent mass of `MnSO_(4)` is half its molecular mass when it is converted to

A

`Mn_(2)O_(3)`

B

`MnO_(2)`

C

`MnO_(4)^(-)`

D

`MnO_(4)^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
B

The equivalent mass will be half the molecular mass when the change in 0.N of Mn is 2
In `MnSO_(4)` , O.N. of Mn = +2
In `Mn_(2)O_(3)` , O.N. of Mn = +3
In `MnO_(2)` , O.N of Mn = +4
In `MnO_(4)^(-)` , O.N of Mn = +7
In `MnO_(4)^(2-)` , O.N of Mn = +6
Thus, O.N. of Mn changes from +2 to +4 when `MnSO_(4)` is converted to `MnO_(2)`
`:.` (b) is the correct answer.
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Statement-1: Equivalent mass of KMnO_(4) is equal to one-third of its molecular mass when it acts as an oxidising agent in an alkaline medium. Statement-2: Oxidation number of Mn is +7 in KMnO_(4) .