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For the reaction, I^(-)+CIO(3)^(-)+H(2...

For the reaction,
`I^(-)+CIO_(3)^(-)+H_(2)SO_(4)rarrCI^(-)+HSO_(4)^(-)+I_(2)` the correct statement (s) in the balanced equation `is//are`

A

stoichiometric coeffiecient of `HSO_(4)^(-)` is 6

B

iodide is oxidised

C

suphur is reduced

D

`H_(2)O` is one of the products

Text Solution

Verified by Experts

The correct Answer is:
A, B, D

The oxidation half reaction is:
`2I^(-)rarrI_(2)+2e^(-)`
The reduction half rection is :
`6H^(+)+CIO_(3)^(-)+6E^(-)rarrCI^(-)+3H_(2)O`
Multiply eqn.(i) by 3 and add to eqn.(i)
`6H^(+)+CIO_(3)^(-)+6e^(-)rarrCI^(-)+3H_(2)O`
`6I^(-)rarr3I_(2)+6e^(-)`
`(6I^(-)+6H^(+)+CIO_(3)^(-)rarr3I_(2)+3H_(2)O+CI^(-))/((a) "The stoichiometry of" HSO_(4)^(-) is 6`
The `H^(+) "ions are provided by" H_(2)SO_(4) "or" HsO_(4)^(-)` ion
(b) `I^(-)` ions are oxidisded to `I_(2)`
(d) `H_(2)O` is one of the products formed in the redox rection.
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