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Although first ionisation potnetial of b...

Although first ionisation potnetial of boron (8-3eV) is less than that of gold (9.22eV).yet the former is a non-metal while the latter is a metal. Explain.

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This is becaue of the difference in the crystal structures of thse elements. Co-ordination number of gold (12) is very high as compared to that of boron (6 or even less),. Since metals have generally high co-ordination numbers while non-metals have smaller value, gold is a metal depsite its higher ionisation potential compared to boron.
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DINESH PUBLICATION-P BLOCK ELEMENTS (GROUP 13 AND 14 )-Concept based
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  2. (p pi-p pi) back bonding occurs in the halides of boron but not in th...

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  3. Although first ionisation potnetial of boron (8-3eV) is less than that...

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  4. An aqueous solution of sodium hydroxide is added dropwise to solution ...

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  5. Why carbon froms covalent compounds whereas lead forms ionic compounds...

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  6. Why PbX2 is more stable than PbX4?.

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  7. Carbon and silicon are mainly tetravalent while germanium, tin and lea...

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  8. Carbon dioxide is a gas but silica is a solid because:

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  9. Trisilicylamine is a weaker bse than trimethylamine. Explain.

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  10. Why is SiCl(4) readily hydrolysed but C Cl(4) is resistant to hydrolys...

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  11. Why trimethylamine is pyramidal but trisilylamine is planar ?

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  12. Write the balanced equation for the following ractions. (i) SnO is ...

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  13. On heating a borate with ethyl alcohol and cone. H(2)SO(4), a green ed...

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  14. What happens when (write chemical equations): (a) Orthoboric acid is...

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  16. How would you explain the lower atomic radii of Ga as compared to Al?

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  18. AIF(3) is insoluble in anhydrous HF but when little KF is added to the...

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  19. Answer the following: (a) Why is BBr(3) a stronger Lewis acid as com...

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  20. BCl(3) is trigonal planr while AlCl(3) is tetrahedral in dimeric state...

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