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Carbon and silicon are mainly tetravalen...

Carbon and silicon are mainly tetravalent while germanium, tin and lead also show divalency. Explain.

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This is explained on the basis of inert pair effect which is significant only in elements with large values of atomic numbers. The general electronic configuration of the elements is `ns^(2)np^(2)`. Because of inert pair effect, in case of `1^st` three elements, the valence `p-`electrons readily become available for bonding while the valence x-electrons remain attached to the nucleus. Thus, these elements show divalency while the first two elements in the absence of inert pair effect are tetravalent.
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DINESH PUBLICATION-P BLOCK ELEMENTS (GROUP 13 AND 14 )-Concept based
  1. Why carbon froms covalent compounds whereas lead forms ionic compounds...

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  2. Why PbX2 is more stable than PbX4?.

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  3. Carbon and silicon are mainly tetravalent while germanium, tin and lea...

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  4. Carbon dioxide is a gas but silica is a solid because:

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  5. Trisilicylamine is a weaker bse than trimethylamine. Explain.

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  6. Why is SiCl(4) readily hydrolysed but C Cl(4) is resistant to hydrolys...

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  7. Why trimethylamine is pyramidal but trisilylamine is planar ?

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  8. Write the balanced equation for the following ractions. (i) SnO is ...

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  9. On heating a borate with ethyl alcohol and cone. H(2)SO(4), a green ed...

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  10. What happens when (write chemical equations): (a) Orthoboric acid is...

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  11. Select the false statements from the following and try to justify your...

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  12. How would you explain the lower atomic radii of Ga as compared to Al?

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  13. Aluminium shows +3 oxidation staet in its compounds but in case of las...

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  14. AIF(3) is insoluble in anhydrous HF but when little KF is added to the...

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  15. Answer the following: (a) Why is BBr(3) a stronger Lewis acid as com...

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  16. BCl(3) is trigonal planr while AlCl(3) is tetrahedral in dimeric state...

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  17. Why is SIF(4) a stronger Lewis acid a s compared to SiCl(4)?

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  18. Hallides of boron and aluminium are Lewis Acids. Assign reason.

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  19. Anhydrous AlCl(3) is covalent but hydrated AlCl(3) is electrovalent. ...

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  20. Why no visible reaction occurs when aluminium is left in contact with ...

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