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On the basis of information available fr...

On the basis of information available from the reaction
`(4)/(3)Al+O_(2) rarr (2)/(3)Al_(2)O_(3),DeltaG = -827kJ mol^(-1)` of `O_(2)`, the minimum emf required to carry out of the electrolysis of `Al_(2)O_(3)` is `(F=96,500 C mol^(-1))`

A

`2.14" V "`

B

`4.28" V "`

C

`6.42" V "`

D

`8.56" V "`

Text Solution

Verified by Experts

The correct Answer is:
B

(b) `DeltaG=-nFE^(@)`cell.
`E^(@)=(-DeltaG)/(nF)=-((-827000))/(2xx96500)=4.28" V "`
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