Home
Class 12
CHEMISTRY
A reaction is second order with respect...

A reaction is second order with respect to a reaction. How is the rate of reaction affected if the
(a) doubled, (b) reduced to `1//2`?

Text Solution

Verified by Experts

Let the reaction , `Ato` products.
Reaction rate (r ) = `k[A]^(2)` (for second order reaction)
i) When concentration is doubled, the rate of reaction may be expressed as:
Reaction rate `(r^(')) = k[2A]^(2)`
`r^(')//r = (k[2A]^(2))/(k[A]^(2))=4 or r^(')= 4r`
reaction rate becomes four times.
ii) When concentration is reduced to half, the rate of reactioin may be expressed as: Reaction rate `(r^('')) = (k[A//2]^(2))/(k[A]^(2)) = 1//4 or r^('') = 1//4r`
reaction rate will be reduced to `1//4`.
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Short Answer type questions|20 Videos
  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Additional important questions:|16 Videos
  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise NCERT Exercise|1 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    DINESH PUBLICATION|Exercise Unit Test - 1|20 Videos
  • CHEMICAL THERMODYNAMICS AND CHEMICAL ENERGETICS

    DINESH PUBLICATION|Exercise Exercise|507 Videos

Similar Questions

Explore conceptually related problems

A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is (i) doubled (ii) reduced to 1//2 ?

A reaction is of second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is reduced to half ? What is the unit of rate constant of such a reaction ?

A reactions is of second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is reduced to half?

A reaction is of second order with respect to its reactant. How will its reaction rate be affected if the concentration of the reactant is (i) doubled (ii) reduced to half ?

A reaction is second order with respect to reactant A. Given an exmaple of pseudo altered if the concentration of A is: i) doubled ii) reduced to half?

DINESH PUBLICATION-CHEMICAL KINETICS-NCERT in text questions
  1. The decomposition of dimethyl ether leads to the formation of CH(4), H...

    Text Solution

    |

  2. Mention the factors that affect the rate of a chemical reaction.

    Text Solution

    |

  3. A reaction is second order with respect to a reaction. How is the rat...

    Text Solution

    |

  4. What is the effect of temperature on the rate constant of reaction? Ho...

    Text Solution

    |

  5. In a pseudo first order hydrolysis of ester in water, the following re...

    Text Solution

    |

  6. A reaction is first order in A and second order in B i) Write differ...

    Text Solution

    |

  7. In a reaction between A and B, the initial rate of reaction was measur...

    Text Solution

    |

  8. The following data were obtained at 300K for the reaction 2A + B to C+...

    Text Solution

    |

  9. The reaction between A and B is first order with respect to A and zero...

    Text Solution

    |

  10. Calculate the half life of the first order reaction from their rate co...

    Text Solution

    |

  11. The half life for radioactive decay of .^(14)C is 5730 years. An archa...

    Text Solution

    |

  12. The experiment data for decomposition of N(2)O(5)[2N(2)O(5) to 4NO(2) ...

    Text Solution

    |

  13. The rate constant for a first order reaction is 60s^(-1). How much tim...

    Text Solution

    |

  14. During nuclear explosion, one of the products is ""^(90)Sr with half- ...

    Text Solution

    |

  15. For a first order reaction, show that the time required for 99% comple...

    Text Solution

    |

  16. A first order reaction takes 40 minutes for 30% decomposition. Calcula...

    Text Solution

    |

  17. For the decomposition of azoisopropane to hexane and nitrogen at 543 K...

    Text Solution

    |

  18. The following data were obtained during first order thermal decomposit...

    Text Solution

    |

  19. The rate constant for the decomposition of N(2)O(5) at various tempera...

    Text Solution

    |

  20. The rate constant for the decomposition of hydrocarbons is 2.418xx10^(...

    Text Solution

    |