Home
Class 12
CHEMISTRY
The decomposition of hydrocarbon follow...

The decomposition of hydrocarbon follows the equation `k=(4.5xx10^(11)s^(-1))e^(-28000K//T)`
Calculate `E_(a)`.

Text Solution

Verified by Experts

According to Arrhenius equation, `k= Ae^(-Ea//RT)`
According to given data, `k= (4.5 xx 10^(11) s^(-1))e^(-28000k//T)`
On comparing, `-E_(a)/(RT) = -28000/T K`
or `E_(a) = (28000 K) xx ( R) = (28000 K)/T`
or `E_(a) = (28000 K) xx ( R) = (28000 K) xx 8.314 J K^(-1) mol^(-1) = 232.792 kJ mol^(-1)`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Short Answer type questions|20 Videos
  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Additional important questions:|16 Videos
  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise NCERT Exercise|1 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    DINESH PUBLICATION|Exercise Unit Test - 1|20 Videos
  • CHEMICAL THERMODYNAMICS AND CHEMICAL ENERGETICS

    DINESH PUBLICATION|Exercise Exercise|507 Videos

Similar Questions

Explore conceptually related problems

The decomposition of N_(2)O into N_(2) and O in the presence of gaseous argon follows second kinetics with k=(5.0xx10^(11) L "mol"^(-1) s^(-1))e^(-29000 K//T) The energy of activation is

The decomposition of N_(2)O into N_(2) and O in the presence of gaseous argon follows second order kinetics with k=(5.0xx10^(11) L " mol"^(-1)s^(-1))e^(-29000 K//T) The activation energy for the reaction E_(a) is

The rate constant of decomposition of methyl nitrite (K_(1)) and ethyl nitrite (K_(2)) follow the equations. K_(1)(s^(-1))=10^(13)e^([(-152.3xx10^(3))/(RT)Jmol^(-1)]) and K_(2)(s^(-1))=10^(14)e^([(-152.3xx10^(3))/(RT)Jmol^(-1)]) Calculate the temperature at which both have same rate of decomposition if 0.1M of each is taken and both show I order kinetics.

The rate constant for a second order reaction is given by k=(5 times 10^11)e^(-29000k//T) . The value of E_a will be:

DINESH PUBLICATION-CHEMICAL KINETICS-NCERT in text questions
  1. The following data were obtained at 300K for the reaction 2A + B to C+...

    Text Solution

    |

  2. The reaction between A and B is first order with respect to A and zero...

    Text Solution

    |

  3. Calculate the half life of the first order reaction from their rate co...

    Text Solution

    |

  4. The half life for radioactive decay of .^(14)C is 5730 years. An archa...

    Text Solution

    |

  5. The experiment data for decomposition of N(2)O(5)[2N(2)O(5) to 4NO(2) ...

    Text Solution

    |

  6. The rate constant for a first order reaction is 60s^(-1). How much tim...

    Text Solution

    |

  7. During nuclear explosion, one of the products is ""^(90)Sr with half- ...

    Text Solution

    |

  8. For a first order reaction, show that the time required for 99% comple...

    Text Solution

    |

  9. A first order reaction takes 40 minutes for 30% decomposition. Calcula...

    Text Solution

    |

  10. For the decomposition of azoisopropane to hexane and nitrogen at 543 K...

    Text Solution

    |

  11. The following data were obtained during first order thermal decomposit...

    Text Solution

    |

  12. The rate constant for the decomposition of N(2)O(5) at various tempera...

    Text Solution

    |

  13. The rate constant for the decomposition of hydrocarbons is 2.418xx10^(...

    Text Solution

    |

  14. Consider a certain reaction A rarr Products with k=2.0xx10^(-2)s^(-1)....

    Text Solution

    |

  15. Sucrose decomposes in acid solution into glucose and fructose accordin...

    Text Solution

    |

  16. The decomposition of hydrocarbon follows the equation k=(4.5xx10^(11)...

    Text Solution

    |

  17. The rate constant for the first order decomposition of a certain react...

    Text Solution

    |

  18. The decomposition of A into product has value of k as 4.5xx10^(3)s^(-...

    Text Solution

    |

  19. The time required for 10% completion of a first order reaction at 298K...

    Text Solution

    |

  20. The rate of a reaction quadruples when the temperature changes from 29...

    Text Solution

    |