Home
Class 12
CHEMISTRY
Consider the decomposition of hydrogen p...

Consider the decomposition of hydrogen peroxide in the alkaline medium which is catalysed by iodide ions.
This reaction takes place in two steps as given below
step-1 `H_(2)O_(2) + I^(-1) to H_(2)O + IO^(-)(Slow)`
Step II `H_(2)O_(2) + IO^(-) to H_(2)O + I^(-) +O_(2)` (fast)
a) Write the rate law expression and determine the order of reactan w.r.t `H_(2)O_(2)`
b) What is the molecularity of each individual step?

Text Solution

Verified by Experts

a) Rate law expression:
Rate = `k[H_(2)O_(2)][I^(-)]`
Order of reaction w.r.t `H_(2)O_(2)=1`
b) Molecularities of both step-I and step-II are two.
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Higher order thinking skills (hots) question|18 Videos
  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Multiple Choice Questions|32 Videos
  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Long Answer type question|14 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    DINESH PUBLICATION|Exercise Unit Test - 1|20 Videos
  • CHEMICAL THERMODYNAMICS AND CHEMICAL ENERGETICS

    DINESH PUBLICATION|Exercise Exercise|507 Videos
DINESH PUBLICATION-CHEMICAL KINETICS-Qestions from board examinations
  1. For a chemical reaction, variation in concentration , in [R] vs time (...

    Text Solution

    |

  2. Catalyst have no effect on the equilibrium constant. Why?

    Text Solution

    |

  3. Consider the decomposition of hydrogen peroxide in the alkaline medium...

    Text Solution

    |

  4. What is half life period ? Calculate the half life period for zero ord...

    Text Solution

    |

  5. Explain the following: a) Effect of catalyst on reaction rate. b M...

    Text Solution

    |

  6. Identify the reaction order from each of the following units of reacti...

    Text Solution

    |

  7. On increasing temperature, activation energy for a reaction decrease. ...

    Text Solution

    |

  8. Prove that the half-life period for a first order reaction is quite in...

    Text Solution

    |

  9. For a reaction A+B to P, the rate law is given by: r=k[A]^(1//2)[B]^...

    Text Solution

    |

  10. A first order reaction is found to have a rate constant k= 5.5 xx 10^(...

    Text Solution

    |

  11. what is the activation energy? How is rate constant related to activat...

    Text Solution

    |

  12. If the rate constant for a reaction is expressed as: rate = k[A]^(2)[B...

    Text Solution

    |

  13. Give an example of second order reaction.

    Text Solution

    |

  14. Write note on activation energy.

    Text Solution

    |

  15. Write two differences between 'order of reaction' and 'molecularity of...

    Text Solution

    |

  16. Explain : Pseudo First Order Reaction

    Text Solution

    |

  17. For the first order reaction with rate contant k, which expression giv...

    Text Solution

    |

  18. What is activated complex?

    Text Solution

    |

  19. What is half life period ? Calculate the half life period for zero ord...

    Text Solution

    |

  20. i) Write the mathematics expressions relating the variation of the rat...

    Text Solution

    |