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The reaction : N(2)O(5)( "in" (C)Cl(4)...

The reaction :
`N_(2)O_(5)( "in" (C)Cl_(4) "solution") to2NO_(2)("same solution") +1//2O_(2)(g)` is of first order in `N_(2)O_(5)` with rate constant = `6.2 xx 10^(-4)s^(-1)`. What is the value of the rate of reaction when `[N_(2)O_(5)]` with rate constant = `6.2 xx 10^(-4)s^(-1)`. What is the rate of reaction when `N_(2)O_(5)=12.5 mol L^(-1)`?

A

`5.15 xx 10^(-5) mol L^(-1)s^(-1)`

B

`6.35 xx 10^(-3) mol L^(-1)s^(-1)`

C

`7.75 xx 10^(-4)molL^(-1)s^(-1)`

D

`3.85 xx 10^(-4) mol L^(-1)s^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
C

c) rate `=k xx [N_(2)O_(5)]`
`(6.2 xx 10^(-4) s^(-1)) xx (1.25 mol L^(1))`
`7.75 xx 10^(-4) mol L^(-1)s^(-1)`
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The reaction N_(2)O_(5) (in C Cl_(4) solution) rarr 2NO_(2) (solution) +(1)/(2) O_(2)(g) is of first order in N_(2)O_(5) with rate constant 6.2 xx 10^(-1) s^(-1) . What is the value of rate of reaction when [N_(2)O_(5)] = 1.25 mole ?

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