Home
Class 12
CHEMISTRY
In a second order reaction, when the con...

In a second order reaction, when the concentration of both the reactants are equal, the reaction is completed `20%` in 500 s. How long would it take for the reaction to go to `60%` completion?

A

3000s

B

5000s

C

1000 s

D

2000s

Text Solution

Verified by Experts

The correct Answer is:
A

a) For the second order reaction,
`k=1/(t xx a). (X/(a-x))`
According to available data, in the first case
t=500s , a=100
a-x `=80%` of 100 = 80
`k=(1 xx 20)/(500s xx 100 xx 80)= 5 xx 10^(-6)s^(-1)`
In the second case, a=100
`(a-x) = 40%` of 100 = 40
`t=(1 xx 60)/((5 xx 10^(-6)s^(-1)) xx (100 xx 40))=3000s`.
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Comprehension type|14 Videos
  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Stright objective types MCQs|24 Videos
  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Effect of temperature and catalyst on rate of reaction.|15 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    DINESH PUBLICATION|Exercise Unit Test - 1|20 Videos
  • CHEMICAL THERMODYNAMICS AND CHEMICAL ENERGETICS

    DINESH PUBLICATION|Exercise Exercise|507 Videos
DINESH PUBLICATION-CHEMICAL KINETICS-Select the correct answer.
  1. For the reaction X-Y, the concentration of X are 1.2 M, 0.6M, order of...

    Text Solution

    |

  2. Consider a first order gas phase decomposition reaction given below: ...

    Text Solution

    |

  3. In a second order reaction, when the concentration of both the reactan...

    Text Solution

    |

  4. A graph plotted between log t(50%) vs log concentration in a straight ...

    Text Solution

    |

  5. The difference rate law for the reaction H(2) +I(2) to 2HI is

    Text Solution

    |

  6. The integrated rate equation is: Rt = log C(0) - log C(r) The stra...

    Text Solution

    |

  7. In respect of the equation k=Ae^(-Ea//RT) in chemical kinetics, which ...

    Text Solution

    |

  8. The rate law for a reaction between the substances A and B is given by...

    Text Solution

    |

  9. For the reaction system 2NO(g) + O(2)(g) rarr 2NO(g) volume is suddenl...

    Text Solution

    |

  10. The rate equation for the reactions 2A + B to C is found to be: rate =...

    Text Solution

    |

  11. t(1//4) can be taken as the time taken for concentration of reactant t...

    Text Solution

    |

  12. A reaction was found to be of second order with respect to concentrati...

    Text Solution

    |

  13. The rate of reaction can be expressed by Arrhenius equation R=Ae^(-K//...

    Text Solution

    |

  14. A radioactive element gets spilled over the floor of a room. Its half ...

    Text Solution

    |

  15. Consider a reaction 2A +B to Products. When the concentration of B alo...

    Text Solution

    |

  16. The energies of activation for forward and reverse reaction for A(2)+...

    Text Solution

    |

  17. For a reaction 1//2A to 2B, rate of disappearance of A is related to t...

    Text Solution

    |

  18. The half life period of a first order chemical reaction is 6.93 minute...

    Text Solution

    |

  19. The time for half life period of a certain reaction A to Products A is...

    Text Solution

    |

  20. Consider the reaction, Cl(2)(aq) + H(2)S(aq) rarr S(s) + 2H^(+) (aq)...

    Text Solution

    |