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Consider the reaction, Cl(2)(aq) + H(2...

Consider the reaction,
`Cl_(2)(aq) + H_(2)S(aq) rarr S(s) + 2H^(+) (aq) + 2Cl^(-)(aq)`
The rate equation for this reaction is,
Rate `=k [Cl_(2)][H_(2)S]`
Which of these mechanisms is`//`are consistent with this rate equation ?
(I) `Cl_(2) + H_(2)S rarr H^(+) + Cl^(-) + Cl^(+) + HS^(-)` (slow)
`Cl^(+) + HS^(-) rarr H^(+) + Cl^(-) + S` (fast)
(II) `H_(2)S hArr H^(+) +HS^(-)` (fast equilibrium)
`Cl^(+) + HS^(-) rarr 2 Cl^(-) + H^(+) + S` (slow)

A

A only

B

B only

C

Both A and B

D

Neither A nor B

Text Solution

Verified by Experts

The correct Answer is:
A

The given rate equation is constant with mechanism A,
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