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Why is BiH(3) the strongest reducing age...

Why is `BiH_(3)` the strongest reducing agent amongst all the hydrides of group `15` elements ?

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Down the group, the atomic size of an element increases and the bond length of the corresponding `E-H` bond also increases. This adversely affects the bond dissociation enthalpy. This means that amongst the trihydrides of the members of nitrogen family, the bond dissociation enthalpy of `Bi-H `bond is the least. Therefore, `BiH_(3)` is the strongest reducing agent among the hydrides of group `15` elements.
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DINESH PUBLICATION-THE P-BLOCK ELEMENTS -N.C.E.R.T In-Text Questions
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  9. What happens when PCl(5) is heated ?

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  11. What is the basicity of H(3)PO(4) ?

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  12. What happens when phosphorus acids (H(3)PO(3)) is heated ?

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  13. List the important sources of sulphur.

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  18. Why does O(3) act as a powerful oxidising agent ?

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  19. How is O(3) estimated quantitatively ?

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