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Can PCl(5) act as oxidising as well as r...

Can `PCl_(5)` act as oxidising as well as reducing agent ? Justify.

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In general, the molecules of a substance can behave as a reducing agent if the central atom is in a position to increase its oxidation number. Similarly, they can act as an oxidising agent if the central atom is in a position to decrease its oxidation number. Now, the maximum oxidation state or oxidation number of phosphorus (P) is `+5`. It cannot increase the same but at the sametime can decrease its oxidation number. In `PCl_(5)`, oxidation number of P is already `+5`. It therfore, cannot act as a reducing agent. However it can behave as an oxidising agent in certain reactions in which its oxidation number decreases. For example,
`2Ag+overset(+5)PCl_(5) to 2AgCl+overset(+3)PCl_(3)`
`Sn+2overset(+5)PCl_(5) to SnCl_(4)+2overset(+3)PCl_(3)`
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DINESH PUBLICATION-THE P-BLOCK ELEMENTS -N.C.E.R.T. Exercise
  1. Why does nitrogen show catenation properties less than prosphorus.

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  2. Give one disproportionation reaction of phosphorus acid (H(3)PO(3)).

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  3. Can PCl(5) act as oxidising as well as reducing agent ? Justify.

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  4. Justify the placement of O, S, Se, Te and Po in the same group of the ...

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  5. Why is dioxygen a gas but sulphur a solid?

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  6. Knowing the electron gain enthalpy values for O to O^(-) " and " O to...

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  7. Which aerosols deplete ozone ?

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  8. The catalyst used in the manufacture of H(2)SO(4) by contact process i...

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  9. How is SO(2) an air pollutant ?

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  10. Why are halogens strong oxidising agents ?

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  11. Explain why does fluorine form only one oxoacid (HOF).

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  12. Explain why inspite of nearly the same electronegativity, nitrogen for...

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  13. Write two uses of ClO2.

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  14. Why are halogens coloured?

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  15. Write redox reactions between fluorine and water.

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  16. How can you prepare Cl2 from HCl and HCI from Cl2? Write reactions onl...

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  17. What inspired N. Bartlett for carrying out reaction between Xe and PtF...

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  18. What are the oxidation states of phosphorus in the following: (i)H(3...

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  19. Write balanced equation for the following: (i). NaCl is heated with ...

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  20. Xenon does not form fluorides such as XeF(3) and XeF(5). Explain.

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