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Justify the placement of O, S, Se, Te an...

Justify the placement of O, S, Se, Te and Po in the same group of the periodic table in terms of electronic configuration, oxidation states and hydride formation.

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The members of the oxygen family are placed in group 16 of p-block. Their inclusion in the same group is justified on the basis of following characteristics.
1. Electronic configuration. Members of the family has `ns^(2)p^(4)` configuration. Their group (10+6) is 16.
2. Oxidation states. With exception of oxygen which exhibits -2 oxidation state in its compounds `(OF_(2) " and " H_(2)O_(2)` are exceptions), rest of the members of the family show varible oxidation states `(-2, +2, +4, +6)` in their compounds.
3. Hydride formation. All the members of the family form covalent hydrides `(MH_(2))` in which the central atom is `sp^(3)` hybridised. These have angular structures and their characteristics show regular gredation.
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DINESH PUBLICATION-THE P-BLOCK ELEMENTS -N.C.E.R.T. Exercise
  1. Give one disproportionation reaction of phosphorus acid (H(3)PO(3)).

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  2. Can PCl(5) act as oxidising as well as reducing agent ? Justify.

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  3. Justify the placement of O, S, Se, Te and Po in the same group of the ...

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  4. Why is dioxygen a gas but sulphur a solid?

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  5. Knowing the electron gain enthalpy values for O to O^(-) " and " O to...

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  6. Which aerosols deplete ozone ?

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  7. The catalyst used in the manufacture of H(2)SO(4) by contact process i...

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  8. How is SO(2) an air pollutant ?

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  9. Why are halogens strong oxidising agents ?

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  10. Explain why does fluorine form only one oxoacid (HOF).

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  11. Explain why inspite of nearly the same electronegativity, nitrogen for...

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  12. Write two uses of ClO2.

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  13. Why are halogens coloured?

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  14. Write redox reactions between fluorine and water.

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  15. How can you prepare Cl2 from HCl and HCI from Cl2? Write reactions onl...

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  16. What inspired N. Bartlett for carrying out reaction between Xe and PtF...

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  17. What are the oxidation states of phosphorus in the following: (i)H(3...

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  18. Write balanced equation for the following: (i). NaCl is heated with ...

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  19. Xenon does not form fluorides such as XeF(3) and XeF(5). Explain.

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  20. With which neutral molecule is ClO^(-) isoelectronic ? Is this molecul...

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