Home
Class 12
CHEMISTRY
NF(3) is not hydrolysed while NCl(3) can...

`NF_(3)` is not hydrolysed while `NCl_(3)` can be readily hydrolysed. Explain.

Text Solution

Verified by Experts

Nitrogen does not have vacant 2d-orbitals in its valence shell. Therefore, it cannot extend its covalency beyond three. As a result, the molecule of `NF_(3)` can exist but not that of `NF_(5)`.
Promotional Banner

Topper's Solved these Questions

  • THE P-BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise Higher Order Thinking Skills|11 Videos
  • THE P-BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise Problems For Practice|54 Videos
  • THE P-BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise Long Answer Type Questions|3 Videos
  • THE OXYGEN FAMILY

    DINESH PUBLICATION|Exercise PREPARATORY PACKAGE|14 Videos

Similar Questions

Explore conceptually related problems

Explain the following situations : (i) In the structure of HNO_(3) molecule , the N-O bond (121 pm) is shorter than N-OH bond (140pm). (ii) SF_(4) is easily hydrolysed whereas SF_(6) is not easily hydrolysed. (iii) XeF_(2) has a straight linear structure and not a bent angular structure.

SF_(6) is not easily hydrolysed whereas SF_(4) can be. Assign reason.

C Cl_(4) is inert towards hydrolysis but SiCl_(4) is readily hydrolysed because

C Cl_(4) does not show hydrolysis but SiCl_(4) is readily hydrolysed because:

DINESH PUBLICATION-THE P-BLOCK ELEMENTS -Questions From Board Examinations
  1. The correct decreasing order of the acidic strength of HClO, HClO(2), ...

    Text Solution

    |

  2. Why is nitric oxide paramagnetic in gaseous state but the solid obtain...

    Text Solution

    |

  3. NF(3) is not hydrolysed while NCl(3) can be readily hydrolysed. Explai...

    Text Solution

    |

  4. All bonds in the molecule of PCl(5) are not equivalent. Explain.

    Text Solution

    |

  5. Assertion: HClO(4) is a stronger acid than HClO(3). Reason: Oxidatio...

    Text Solution

    |

  6. Bleaching powder is prepared by passing chlorine into

    Text Solution

    |

  7. Addition of Cl(2) to KI solution give its a brown colour but excess...

    Text Solution

    |

  8. Why does H(3)PO(3) act as a reducing agent but H(3)PO(4) does not ?

    Text Solution

    |

  9. The compound which could not act both as oxidising and reducing agent ...

    Text Solution

    |

  10. Phosphorus acid can act both as oxidising agent as well as reducing ag...

    Text Solution

    |

  11. Assertion : Fluorine is the strongest oxidising agent in halogens. R...

    Text Solution

    |

  12. What happen when Cl(2) is passed through a hot concentrated solution o...

    Text Solution

    |

  13. XeF(4) on partial hydrolysis produces

    Text Solution

    |

  14. PH(3) has lower boiling point that NH(3). Why ?

    Text Solution

    |

  15. Why does PCl(3) fumes in air ?

    Text Solution

    |

  16. Which set of elements have strongest tendency to form anions ?

    Text Solution

    |

  17. Molecular shape of SF(4), CF(4) and XeF(4) are

    Text Solution

    |

  18. Write the balanced equation for the following chemical reaction: "Hy...

    Text Solution

    |

  19. Write the balanced chemical equations for the following. (i)Hypophos...

    Text Solution

    |

  20. The oxidation states exhibites by hydrogen in its various compounds ar...

    Text Solution

    |