Home
Class 12
CHEMISTRY
Sulphur vapours exhibit some paramagneti...

Sulphur vapours exhibit some paramagnetic behaviour. Explain.

Text Solution

Verified by Experts

In the vapour state, sulphur exists as `S_(2)` molecule just like oxygen `(O_(2))`. It is paramagnetic in nature due to the presence of unpaired electrons in the antibonding `pi^(**)` orbitals.
Promotional Banner

Topper's Solved these Questions

  • THE P-BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise Higher Order Thinking Skills|11 Videos
  • THE P-BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise Problems For Practice|54 Videos
  • THE P-BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise Long Answer Type Questions|3 Videos
  • THE OXYGEN FAMILY

    DINESH PUBLICATION|Exercise PREPARATORY PACKAGE|14 Videos

Similar Questions

Explore conceptually related problems

Why sulphur in vapour state exhibits paramagnetic behaviour at above 800^(@)C

Account for the following : (i) Sulphur in vapour from exhibits paramagnetic behavious. (ii) SnCl_(4) is more covalent the SnCl_(2) . (iii) H_(3)PO_(2) is a stronger reducing agent then H_(3)PO_(3) .

(a) What happens when : (i) HCl reacts with finely powdered iron. (ii) Cl_(2) reacts with hot concentrated solution of NaOH. (b) Give appropriate reason for each of the following : (i) Sulphur vapour exhibits some paramagnetic character. (ii) NH_(3) more basic than PH_(3) . (iii) Dioxygen is a gas but sulphur a solid.

Oxygen and sulphur in vapour phases are paramagnetic in nature. Explain why ?

Form of sulphur which shows paramagnetic behaviour

Statement-1 : Sulphur exhibits paramagnetic behaviour in vapour state. Statement-2 : In vapour state sulphur partly exists as S_(2) molecule which has two unpaired electrons in antibonding pi^(**) orbitals.

DINESH PUBLICATION-THE P-BLOCK ELEMENTS -Questions From Board Examinations
  1. Give one use of lichen

    Text Solution

    |

  2. Bi(V) and Sb(V) which may be a stronger oxidizing agent and why ?

    Text Solution

    |

  3. Sulphur vapours exhibit some paramagnetic behaviour. Explain.

    Text Solution

    |

  4. Complete the following chemical equations : (i) P(4) (s) +NaOH (aq) ...

    Text Solution

    |

  5. In the structure of HNO(3), why is N-O bond (121 pm) shorter than N-OH...

    Text Solution

    |

  6. XeF(2) has linear structure and not a bent structure , Given reason .

    Text Solution

    |

  7. Red phosphorus is less reactive than yellow phosphorus because

    Text Solution

    |

  8. On the basis of VSEPR theory, prefict the shapes of the following mole...

    Text Solution

    |

  9. Why helium and neon do not form compounds with florine?

    Text Solution

    |

  10. Ka(1), Ka(2) and Ka(3) are the respective constants for the following ...

    Text Solution

    |

  11. Give the decreasing order of dipole moments of HF,HCI,HBr, and HI.

    Text Solution

    |

  12. (a) Why does NO2 dimerise ? (b) In what way can it be proved that PH...

    Text Solution

    |

  13. Red phosphorus is ...............reactive than white phosphorus as red...

    Text Solution

    |

  14. NF(3) is not hydrolysed while NCl(3) can be readily hydrolysed. Explai...

    Text Solution

    |

  15. Among CIF(3), BF(3) and NH(3) molencules the one with non-planar geome...

    Text Solution

    |

  16. Complete the following equations : (i) underset(("hot and conc."))(N...

    Text Solution

    |

  17. The stability of +5 oxidation state decreases down the group 15 of the...

    Text Solution

    |

  18. The negative value of electron gain enthalpy is less for fluorine than...

    Text Solution

    |

  19. Which of the following correct about [Icl(4)]^(-) and iCl(4) compound

    Text Solution

    |

  20. Why does H(3)PO(3) act as a reducing agent but H(3)PO(4) does not ?

    Text Solution

    |