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In which one of the following species , ...

In which one of the following species , the central atom has the tuype of hybdridiztion which is not the same as that present in other three?

A

`SF_(4)`

B

`I_(3)^(-)`

C

`SbCl_(5)^(2-)`

D

`PCl_(5)`

Text Solution

Verified by Experts

The correct Answer is:
B

`SF_(4), H=(1)/(2)(+4-0+0)=5(sp^(3)d)`
`I_(3)^(-) , H=(1)/(2)(7+2-0+3)=6(sp^(3)d^(2))`
`(SbCl_(5))^(2-),H=(1)/(2)(5+5-0+2)=5(sp^(3)d)`
`PCl_(5) , H=(1)/(2) (5+5-0+0)=5 (sp^(3)d)`
`therefore` (b) is the correct answer.
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