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Asserartion:PCl(5) is covalent in gaseou...

Asserartion:`PCl_(5)` is covalent in gaseous and liquide states but ionic in solid state.
Reason: `PCl_(5)` in solid state consits of tetrahhedral `PCl_(4)^(+)` cation and octahedral `PCl_(6)^(-)` anion.

A

If both assertion and reason are correct and reason is correct explanation for assertion.

B

If both assertion and reason are correct but reason is not correct explanation for assertion.

C

If assertion is correct but reason is incorrect.

D

If both assertion and reason are incorrect.

Text Solution

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The correct Answer is:
B

Correct explanation : In the gaseous and liquid states, `PCl_(5)` exists as descrete covalent molecule molecules. But in the solid state, as `PCl_(4)^(+) " and " PCl_(6)^(-)` ions which are attracted to each other.
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Assertion : PCl_(5) is covalent in gaseous and liquid state but ionic in solid state. Reason: PCl_(5) in solid state consists of tetrahedral PCl_(4)^(+) cation and octahedral PCl_(6)^(-) anion.

The compound is covalent in gaseous state but ionic in solid state is.

Statement-1 : PCl_(5) is covalent in gaseous and liquid state but ionic in solid state. Statement-2 : The solid state of PCl_(5) consists of tetrahderal cation and octahedral anion.

PCl_5 in solid state exists as.

The structure of PCl_(5) in the solid state is :

Hybridization in phosphorus in PCl_5 in solid state

Hybridisation of PCl_(5) solid is :

In solid state PCl_(5) is a

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