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How would you account for the following ...

How would you account for the following ?
(i) Many of the transition elements are known to form interstitial compound ?
(ii) The metallic radii of third (5d) series of transition metals are virtually the same as those of the corresponding group member of second (4d) series.
(iii) Lanthanoids form primarily +3 ions while the actinoids usually have higher oxidation state in their compounds, +4 or even +6 being typical.

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(i)N/A
(ii) N/A
(iii) In the elements belonging to Actionids series 5f, 6d and 7s orbitals have comparable enegies and the electrons present in these orbitals can take part in the bond formation to show higher oxidation states.
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The atomic radii of the metals of the third (5d) series of transitions elements are virtually the same as those of the corresponding members of the second (4d) series. Explain.

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How will you account for the following ? (i) The metallic radii of the third (5d) series of transition metals are virtually the same as those of the corresponding group members of the second (4d) series. (ii) Lanthanoids form primarily +3 ions while actinoids usually have higher oxidation states in their compounds . Among the lanthanoids, Ln(III) compounds are predominant. However, occasionally in solution or in solid state +2 and +4 ions are obtained. Explain.

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DINESH PUBLICATION-D-AND -F BLOCK ELEMENTS-Question From Board Examination
  1. Metal-Metal bondin is more extensive in the 4d and 5d series of transi...

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  2. Why does Mn(III) undergo disproportionation reaction easily ?

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  3. How would you account for the following ? (i) Many of the transition...

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  4. The colour of the transition metal ions is due to

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  5. Why is the highest oxidation state of a metal exhibited in its oxide o...

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  6. K(2)Cr(2)O(7) is a good oxidising agent in acidic medium. Explain.

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  7. Why is potssium permanganate thermally unstable at 513 K.

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  8. The inter convertibility of chromate ion and dichromate ion in aqueous...

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  9. Complete the following equation : CrO(4)^(2-)+H^(+) to

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  10. Give reasons for the following : (i) Mn^(3+) is a good oxidising ag...

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  11. Predict which of the following will be coloured in aqueous solution ? ...

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  12. (a) Explain the structure of dichromate ion. (b) Why are cadmium sa...

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  13. COMPARISON OF LANTHANOIDS & ACTINOIDS

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  14. Explain the following : (i) Cu^(+) is colourless and Cu^(2+) is colo...

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  15. What do you mean by (a) Chromyl Chloride test (b) Actinoids?

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  16. Why do transition metals form coloured complexes ?

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  17. How would you prepare (i) K(2)MnO(4) and MnO(2)? (ii) Na(2)Cr(2)O(7...

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  18. Why is enthalpy of atomisation is the lowest for Zn in 3d series of tr...

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  19. Why is Cr^(2+) reducing and Mn^(3+) oxidising when both have d^4 confi...

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  20. Which of the following actinoids is well known to exhibit +2 oxidation...

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