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What happen when a solution of potassium...

What happen when a solution of potassium chromate is treated with an excess of dil. Nitic acid?

A

`Cr_(2)O_(7)^(2-)` and `OH^(-)` are formed

B

`CrO_(4)^(2-)` is reduced to +3 state of Cr

C

`CrO_(4)^(2-)` is oxidized to +7 state of Cr.

D

`Cr^(3+)` and `Cr_(2)O_(7)^(2-)` are formed.

Text Solution

Verified by Experts

The correct Answer is:
A

`Cr_(2)O_(7)^(2-) + OH^(-) hArr2CrO_(4)^(2-) + H^(+)`
In the acidic medium, the equilibrium gets shifted to left .
Therefore, `Cr_(2)O_(7_^(2-)` and `OH^(-) ions are formed.
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