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Why are Mn^(2+) compounds more stable th...

Why are `Mn^(2+)` compounds more stable than `Fe^(2+)` toward oxidation to their `+3` state?

A

`Mn^(2+)` is more stable with high `3^(nd)` ionisation energy

B

`Mn^(2+)` is bigger in size

C

`Mn^(2+)` has completely filled d-orbitals

D

`Mn^(2+)` does not exist.

Text Solution

Verified by Experts

The correct Answer is:
A

`Mn^(2+) (3d^(5))` is a statle since it has all half-filled orbitals.
`Fe^(2+) (3d^(6))` is yet to acquire a stable configuration since it has one filled orbital.
Therefore, `Fe^(2+)` ion has a tendency to get oxidised to `Fe^(3+)` ion whereas `Mn^(2+)` ion has no urge to participate in the oxidatioxn reaction.
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Why Mn^(2+) compounds are more stable than Fe^(2+) compounds towards oxidation to their + 3 state ?

DINESH PUBLICATION-D-AND -F BLOCK ELEMENTS-JEE (Main ) & other engineering entrance examination
  1. The correct statemet is

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  2. Which is not true for describing the catalyti activity of transitio...

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  3. The electronic configuration of Gd^(2+)is :

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  4. Upon heating poatssium permanganate, which of the following compou...

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  5. The atomic number of cerium (Ce) is 58. The correct electronic con...

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  6. The colour of KMnO(4) is due to

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  7. Which of the following statements is incorrect for KMnO(4)?

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  8. In which of the following d-d transition involves absorption in the ...

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  9. The highest oxidation state exhibited by a transition elements is .

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  10. Which of the following metal ions has a calculated magnetic moment v...

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  11. Which of the following statement regarding lanthandes is false?

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  12. The bivalent metal ion having maximum paramagnetic behaviour among ...

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  13. Why are Mn^(2+) compounds more stable than Fe^(2+) toward oxidation to...

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  14. Which of the following statement is worng regrading lanthanoids?

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  15. The correct basicity order of the following lanthanoid ions is

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  16. When MnO(2) fused with KOH, a coloured compound is formed . The produc...

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  17. Identify the cases(s) where there in change in oxidation number.

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  18. Sodium salt of an organic acid 'X' produces effervescence with conc. H...

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  19. For redox reaction {:(xMnO(4)^(-)+yH(2)C(2)O(4)+ZH^(+)),(" ...

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  20. 1 mole of FeSO(4) (Atomic mass of Fe = 55.84g mol^(-1)) is oxidised ...

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