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For the complex [Fe(en)(2)Cl(2)]Cl (en =...

For the complex `[Fe(en)_(2)Cl_(2)]Cl` (en = ethylene diamine ) , identify
(i) the oxidation number of iron ,
(ii) the hybrid orbitals and the shape of the complex,
(iii) the magnetic behaviour of the complex ,
(iv) the number of geometrical isomers ,
(v) whether there is an optical isomer also , and
(vi) name of the complex . (At. no. of Fe = 26)

Text Solution

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a) `[Fe(en)_(2)Cl_(2)]Cl : x + 0 + 2(-1)=+1` or x`=+3`
b) The complex is octahedral in shape. It has `d^(2)sp^(3)` hybridisation.
c) It is an inner orbital complex. With one unpaired electron, it is paramagnetic in nature. ltbr) d) The complex can exist as two geometrical isomers. These are cis nad trans.

e) cis isomere can exist as two optical isomers.
ltrbgt f) IUPAC name of complex : dichloridobis (ethane -1, 2-diamine) iron(III) chloride.
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For the complex [Fe (en)_2Cl_2]Cl , identify the following: (i) Oxidation number of iron. (ii) Hybrid orbitals and shape of the complex. (iii) Magnetic behaviour of the complex. (iv) Number of its geometrical isomers. (v) whether there may be optical isomer also.