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Specify the oxidation numbers of metals ...

Specify the oxidation numbers of metals in the following co-ordination entites :
(a) `[Co(H_(2)O)(CN)(en_(2))]^(2+)` (b) `[PtCI_(4)]^(2-)`
(c) `[Cr(NH_(3))_(3)CI_(3)]` (D) `[CoBr_(2)(en)_(2)]^(+)`
(e) `K_(3)[Fe(CN)_(6)]`.

Text Solution

Verified by Experts

(a) O.N. Of Co : x + 0 + (-1) + 2 (0) = + 2 (0) = + 2 or x = + 2 + 1 = + 3
(b) O.N. Of Pt : x + 4 (-1) = -2 or x = -2 + 4 = + 2
(c) O.N. Of Cr : x + 3(0) + 3(-1) = 0 or x = + 3
(d) O.N. Of Co : x + 2(-1) + 2(0) = + 1 or x = + 1 + 2 = + 3
(e) O.N. of Fe : x + 6(-1) = - 3 or x = - 3 + 6 = + 3
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DINESH PUBLICATION-CO-ORDINATION COMPOUNDS -NCERT exercise
  1. Explain with two examples each of the following: coordination entity, ...

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  2. What is meant by unidentate and ambidentate ligands? Give two examples...

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  3. Specify the oxidation numbers of metals in the following co-ordination...

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  4. Using IUPAC norms write the fomulas for the following (i). Tetrahydr...

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  5. Using IUPAC norms write the systematic names of the following : (a) ...

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  6. List various types of isomerism possible for coordination compounds, g...

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  7. how many geometrical isomers are posssible in the following coordinati...

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  8. Draw the structures of optical isomers of: (i). [Cr(C2O4)3]^(3-) (...

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  9. Draw all the isomers (geometrical and optical) of: (i) [CoCl(2)(en)(...

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  10. Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how man...

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  11. Aqueous copper sulphate solution (blue in colour) gives: (i). A gree...

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  12. What is the coordination entity formed when excess of aqueous KCN is a...

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  13. Discuss the nature of bonding in the following co-ordination complexes...

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  14. Draw figure to show the splitting of d orbitals in an octahedral cryst...

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  15. What is spectrochemical series? Explain the difference between a weak ...

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  16. What is crystal field splitting energy? How does the magnitude of tria...

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  17. [Cr(NH3)6]^(3+) is paramagnetic while [Ni(CN)4]^(2-) is diamagnetic. E...

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  18. A solution of [Ni(H(2)O)(6)]^(2+) is green but a solution of [Ni(CN)(4...

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  19. [Fe(CN)(6)]^(4-) and [Fe(H(2)O)(6)]^(2+) are of different colours in d...

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  20. Bonding In Metal Carbonyls

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