Home
Class 12
CHEMISTRY
A metal ion M^(n+) having d^(4) valence ...

A metal ion `M^(n+)` having `d^(4)` valence electrode configuration combines with three ligands to form a complex compound. Assuming `Delta_(0)gtP`.
i) Draw the diagram assuming d-orbital splitting during the complex formation.
ii) Write the electronic configuration of valence electrons of the metal `M^(n+)` ion in terms `t_(2g)` and `e_(g)`.
iii) What type of of hybrisation will `M^(n+)` ion have?
iv) Name the type of isomerism exhibited by the complex.

Text Solution

Verified by Experts

i) N/A
ii) When `Delta_(0) gt P`, the electrons get paired up in the lower `t_(2g)` orbitals. The electronic configuration of `d^(4)` ion is: `t_(2g)^(2)e_(g)^(0)`.
iii) The complex is octahedral since the didenate ligands are attached to the `M^(n+)` ion which is `d^(2)sp^(3)` hybridised.
iv) The complex will exhibit optical isomerism.
Promotional Banner

Topper's Solved these Questions

  • CO-ORDINATION COMPOUNDS

    DINESH PUBLICATION|Exercise HIGH ORDER THINKING SKILLS (HOTS) QUESTIONS|10 Videos
  • CO-ORDINATION COMPOUNDS

    DINESH PUBLICATION|Exercise Assignment|76 Videos
  • CO-ORDINATION COMPOUNDS

    DINESH PUBLICATION|Exercise Additional Important Questions|26 Videos
  • CHEMISTRY IN EVERY DAY LIFE

    DINESH PUBLICATION|Exercise Unit test-9|50 Videos
  • CYANIDES, ISOCYANIDES, NITROCOMPOUNDS AND AMINES

    DINESH PUBLICATION|Exercise Unit test - 8|20 Videos
DINESH PUBLICATION-CO-ORDINATION COMPOUNDS -Questions from board examinations
  1. Give the number of unpaired electrons in the following complex ions: ...

    Text Solution

    |

  2. Name the isomerism exhibited by the co-ordination compounds? [Co(NH(...

    Text Solution

    |

  3. A metal ion M^(n+) having d^(4) valence electrode configuration combin...

    Text Solution

    |

  4. a) Give the electronic configuration of the d-orbitals of Ti in [Ti(H(...

    Text Solution

    |

  5. Give an example of linkage isomerism.

    Text Solution

    |

  6. Name the following compounds according to IUPAC system i) [Co(NH(3))...

    Text Solution

    |

  7. Give the shape and behaviour of the following complexes: i) [Co(NH(3...

    Text Solution

    |

  8. Explain the following given appropriate reason: i) Nickel does not f...

    Text Solution

    |

  9. Write the name, the state of hybridization, the shape and the magnetic...

    Text Solution

    |

  10. a) Give the electronic configuration of the d-orbitals of Ti in [Ti(H(...

    Text Solution

    |

  11. a) State the hybridisation & magnetic behaviour of [Cr(CO)(6)] b) Wh...

    Text Solution

    |

  12. Among the octahedral and tetrahedral crystal fields, In which case the...

    Text Solution

    |

  13. (a) Define a ligand. (b) Discuss the magnetic behaviour, nature and ...

    Text Solution

    |

  14. Write the stucture and names of all steresiomers fo the following com...

    Text Solution

    |

  15. Draw the structure of isomers if any and write the names of the follow...

    Text Solution

    |

  16. Give the formula of each of the following coordination entities : (...

    Text Solution

    |

  17. Write the name , structure and magnetic behaviour of the following com...

    Text Solution

    |

  18. Give the electronic configurations of d-orbitals of K(3)[Fe(CN)(6)] an...

    Text Solution

    |

  19. Give the names of the followng complexes according to IUPAC system (...

    Text Solution

    |

  20. Give an account of the valence bond theory . Explain the geometry and ...

    Text Solution

    |