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What is the effect of synergic bonding i...

What is the effect of synergic bonding interactions in a metal carbonyl complex ?

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Because of this, CO acts as a strong field ligand . For details consult section 12 .
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Ligand in a metal carbonyl complex is

The figure represents the synergic bonding interaction in metal carbonyl complex. On the basis of the explain the following: (i) Strength of Metal-ligand bond (ii) Bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.

Assertion: Oxidation state of Fe in Fe(CO)_(5) is zero. Reason: Synergic bonding takes place in this metal carbonyl complex.

Bonding In Metal Carbonyls

Bonding In Metal Carbonyls

In metal carbonyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligands bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide. Simple carbonyls are invariably spin-paired complexes except for vanadium metal. Which one of the following metal carbonyl involves the d^(2)sp^(3) hybridization for the formation of metal-carbon sigma" "bonds and is paramagnetic ?

In metal carbonyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligands bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide. Simple carbonyls are invariably spin-paired complexes except for vanadium metal. Which one of the following metal carbonyls are inner orbital complexes with diamagnetic property ? (P) Ni(CO)_(4)" "(Q) Fe(CO)_(5) (R ) V(CO)_(6)" "(S) Cr(CO)_(6) Select the correct answer from the codes given below :

DINESH PUBLICATION-CO-ORDINATION COMPOUNDS -Questions from board examinations
  1. (a) Write the IUPC names of the following co-ordination compounds (i) ...

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  2. (i) predict the number of unpaired electrons in the tetrahedral [MnBr(...

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  3. What is the effect of synergic bonding interactions in a metal carbony...

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  4. (i) write the IUPAC name of the following complex : [Cr(en)(3)]Cl(3) ...

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  5. (i) Write the geometrical isomer of the complex [Co(en)(2)Cl(2)]^(+) ....

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  6. (i) Write the IUPAC name of the complex : [Ce(NH(3))(2)Cl(2)(en)Cl] . ...

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  7. Write hybridisation and magnetic behaviour of the complex [Ni(CO)(4)].

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  8. Out of CN^(-) and CO , which ligands forms a more stable complex with ...

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  9. What type of isomerism is shown by [Co(NH(3))(5)ONO]Cl(2) ?

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  10. Write the IUPAC names of the complex [Pt(en)(2)Cl(2)]^(2+) . What type...

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  11. Give the chemical formula of the following complexes : (i) diaminesilv...

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  12. When a co-ordination compound CrCl(3).6H(2)O is mixed with AgNO(3), 2 ...

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  13. (a) For the complex [Fe(CN)(6)]^(3-) , write the hybridisation type, m...

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  14. When a coordination complex PtCl(4).6NH(3) is mixed with AgNO(3), 4 mo...

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  15. Why is the complex [CoF6]^(3-) less stable than the complex [Co(en)3]^...

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  16. For the complex , [Co(en)(3)]^(3+) , write the hybridisation type, mag...

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  17. (a) For the complex [Fe(CO)(5)] write the hybridisartion , magnetc cha...

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  18. Explain linkage , isomerism in co-ordinate compounds .

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  19. How does K(2)[PtCl(4)] get ionised when dissolved in water ? Will it f...

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  20. (i) What type of isomerism is shown by the complex [Co(NH(3))(6)] [Cr(...

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