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A metal ion M^(n+) HAVING D^(4) valence ...

A metal ion `M^(n+)` HAVING `D^(4)` valence electronic configuration combines with three bidentate ligands to form a complex compound . Assuming `Delta_(0) gt P` :
(i) write the electronic configuration of `d^(4)` ion .
(ii) what type of hybridisation will `M^(n+)` ion has ?
(iii) Nmae the type of isomerism exhibited by this complex .

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AI Generated Solution

To solve the problem step by step, we will address each part of the question systematically. ### Step 1: Write the electronic configuration of `d^(4)` ion. The `d^(4)` configuration means that there are 4 electrons in the d-orbitals. Given that the complex is formed in an octahedral field and assuming that `Δ₀ > P` (where `Δ₀` is the crystal field splitting energy and `P` is the pairing energy), the electrons will fill according to the crystal field theory. In an octahedral field: - The d-orbitals split into two sets: the lower energy t₂g (three orbitals) and the higher energy eₖg (two orbitals). ...
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DINESH PUBLICATION-CO-ORDINATION COMPOUNDS -Questions from board examinations
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  3. Why is the complex [CoF6]^(3-) less stable than the complex [Co(en)3]^...

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  4. For the complex , [Co(en)(3)]^(3+) , write the hybridisation type, mag...

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  5. (a) For the complex [Fe(CO)(5)] write the hybridisartion , magnetc cha...

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  6. Explain linkage , isomerism in co-ordinate compounds .

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  7. How does K(2)[PtCl(4)] get ionised when dissolved in water ? Will it f...

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  8. (i) What type of isomerism is shown by the complex [Co(NH(3))(6)] [Cr(...

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  9. A metal ion M^(n+) HAVING D^(4) valence electronic configuration combi...

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  10. (a) What type of isomerism is shown by the complex [Co(NH(3))(5)(SCN)]...

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  11. Write IUPAC names of (i) K(3)[Fe(CN)(5)NO] (II) K(3)[Al(C(2)O(4))(3)...

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  12. Write geometrical isomers of [CoCl(3)(NH(3))(3)] .

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  13. (a) Write the formula of the following coordination compound : Iron (I...

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  14. (a) Write the co-ordination number and oxidation state of platinum in ...

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  15. A metal complex having composition Cr(NH(3))(4)CI(2)Br has been isolat...

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  16. (a) Define a ligand . (b) Discuss the magnetic behaviour , nature an...

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  17. What is basic difference between a double salt and a co-ordination com...

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  18. Write the structural formula of the following compounds : (i) Dichlo...

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  19. (a) Write the IUPAC name of the complex : [Co(NH(3))(4)(H(2)O)Cl]Cl(2)...

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  20. [NiCl(4)]^(2-) is paramagnetic while [Ni(CO)(4)] is diamagnetic though...

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